Isaac Scientific Publishing

Modern Organic Chemistry Research

Synthesis of Adamantyl-Containing Compounds - Structure Elements of Rotaxanes and Supramolecular Polymers

Download PDF (343.3 KB) PP. 124 - 129 Pub. Date: August 3, 2017

DOI: 10.22606/mocr.2017.23005

Author(s)

  • Gennady M. Butov*
    Volzhsky Polytechnic Institute (branch) Volgograd State Technical University, Department of Chemistry, Technology and Equipment of Chemical Production, 42a Engels st., Volzhsky, Russia
  • Vladimir Burmistrov

    Volzhsky Polytechnic Institute (branch) Volgograd State Technical University, Department of Chemistry, Technology and Equipment of Chemical Production, 42a Engels st., Volzhsky, Russia
  • Karim R. Saad

    Volzhsky Polytechnic Institute (branch) Volgograd State Technical University, Department of Chemistry, Technology and Equipment of Chemical Production, 42a Engels st., Volzhsky, Russia

Abstract

This manuscript deals with the synthesis of various Adamantane derivatives as objects of supramolecular chemistry, in particular, supramolecular Cyclodextrine polymers (SCP) and Rotaxanes. One of the structural elements of the SCP and Rotaxanes are linear molecules modified by the end-blockers. A considerable volume of adamantyl group allows Adamantane derivatives to create locking groups in Rotaxanes, and a high affinity for β-Cyclodextrine to create supramolecularpolymers.

Keywords

Adamantane, Cyclodextrine, Isocyanate, supramolecular polymer, urea.

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